The reaction of nitrogen traces in plasmas with polymer surfaces
Autor: | Stefan Kröpke, Andreas Holländer |
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Přispěvatelé: | Publica |
Jazyk: | angličtina |
Rok vydání: | 2011 |
Předmět: |
chemistry.chemical_classification
Materials science Argon Trace Amounts Inorganic chemistry chemistry.chemical_element Surfaces and Interfaces General Chemistry Polymer Polyethylene Condensed Matter Physics Nitrogen Surfaces Coatings and Films chemistry.chemical_compound chemistry Impurity Desorption Materials Chemistry Sulfur dioxide |
Popis: | Trace amounts of nitrogen in argon plasmas and in sulfur dioxide plasmas result in the incorporation of nitrogen in the surface of polymers like polyethylene. In vacuum systems with a base pressure in the microbar range the main sources of the nitrogen are leaks and the desorption from the reactor walls. Impurities of the process gas can contribute, too. There is strong evidence, that the nitrogen is first oxidized to nitric oxide which then recombines with radicals at the polymer surface. |
Databáze: | OpenAIRE |
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