A 3:1 site-differentiated [4Fe-4S] cluster immobilized on a self-assembled monolayer
| Autor: | Erwin P. L. van der Geer, Robertus J. M. Klein Gebbink, Bart Hessen, Gerard van Koten, Coenraad R. van den Brom, Petra Rudolf, Laurent Houssiau, Imad Arfaoui |
|---|---|
| Přispěvatelé: | Chemical Biology & Organic Chemistry, Homogene katalyse en materialen, Dep Scheikunde, Zernike Institute for Advanced Materials, Surfaces and Thin Films |
| Rok vydání: | 2008 |
| Předmět: |
Molecular junction
ION MASS-SPECTROMETRY Analytical chemistry Mass spectrometry X-ray photoelectron spectroscopy RAY PHOTOELECTRON-SPECTRA Monolayer Cluster (physics) SYNTHETIC ANALOGS GOLD Physical and Theoretical Chemistry biology Chemistry CARBONYLATION Self-assembled monolayer MOLECULAR JUNCTIONS Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography General Energy Iron-sulfur protein IRON-SULFUR PROTEINS biology.protein ACTIVE-SITES COMPLEXES |
| Zdroj: | Journal of Physical Chemistry C, 112(44), 17225-17230. AMER CHEMICAL SOC |
| ISSN: | 1932-7447 |
| Popis: | A 3:1 site-differentiated [4Fe-4S] cluster is immobilized on a thiol-functionalized self-assembled monolayer (SAM) on Au(111) by thiol-thiolate exchange chemistry. Fe 2p signals observed by X-ray photoelectron spectroscopy support the presence of [4Fe-4S] clusters at the SAM surface; further evidence comes from the detection of n-Bu4N+ and cluster-derived species by secondary-ion mass spectrometry. The immobilizing interaction is sufficiently strong to allow the study of [4Fe-4S] clusters at solid-liquid interfaces. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|