A Ferrocene-Porphyrin Ligand for Multi-Transduction Chemical Sensor Development
| Autor: | Corrado Di Natale, Barbara Floris, Ingemar Lundström, Larisa Lvova, Roberto Paolesse, Pierluca Galloni |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: |
Inorganic chemistry
Potentiometric titration lcsh:Chemical technology opto-potentiometric transduction Settore ING-INF/01 - Elettronica Biochemistry Article Analytical Chemistry Ion chemistry.chemical_compound Teknik och teknologier Organic chemistry lcsh:TP1-1185 porphyrin-ferrocene ligand transition metals detection Electrical and Electronic Engineering Instrumentation Detection limit Chemistry Settore CHIM/07 - Fondamenti Chimici delle Tecnologie Settore CHIM/06 - Chimica Organica Fluorescence Acceptor Porphyrin Atomic and Molecular Physics and Optics Solvent Ferrocene Engineering and Technology |
| Zdroj: | Sensors; Volume 13; Issue 5; Pages: 5841-5856 Sensors (Basel, Switzerland) Sensors, Vol 13, Iss 5, Pp 5841-5856 (2013) |
| ISSN: | 1424-8220 |
| DOI: | 10.3390/s130505841 |
| Popis: | 5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin acceptor sub-units was considered. The simultaneously measured optical and potentiometric responses of solvent polymeric membranes based on H2TFcP permitted the detection of lead ions in sample solutions, in the concentration range from 2.7 × 10(-7) to 3.0 × 10(-3) M. The detection limit of lead determination was 0.27 μM, low enough to perform the direct analysis of Pb2+ in natural waters. |
| Databáze: | OpenAIRE |
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