Reactive Cross-Talk between Adjacent Tension-Trapped Transition States

Autor:	Jeremy M. Lenhardt, Robert Choe, Mitchell T. Ong, James William Ogle, Todd J. Martínez, Stephen L. Craig
Rok vydání:	2011
Předmět:	Cyclopropanes Hot Temperature Polymers Chemistry Tension (physics) Disproportionation General Chemistry Trapping Ring (chemistry) Photochemistry Biochemistry Molecular physics Catalysis Transition state Colloid and Surface Chemistry Isomerism Thermal Isomerization
Zdroj:	Journal of the American Chemical Society. 133:3222-3225
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja107645c
Popis:	Tension along a polymer chain traps neighboring s-trans/s-trans-1,3-diradicals from the mechanically induced ring opening of gem-difluorocyclopropanes (gDFCs). The diradicals correspond to the transition states of the force-free thermal isomerization reactions of gDFCs, and the tension trapping allows a new disproportionation reaction between two simultaneously trapped diradicals to take place.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::897c6a03067289d4d2a0818c7e067bcf https://doi.org/10.1021/ja107645c Zobrazit plný text záznamu