Carbon–Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand
| Autor: | Martyn P. Coles, Claire L. McMullin, Mathew D. Anker, Nasir A. Rajabi |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Carbon disulfide 010405 organic chemistry Chemistry Ligand chemistry.chemical_element General Medicine General Chemistry 010402 general chemistry 01 natural sciences Oxygen Medicinal chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Carbon–carbon bond Carbon monoxide |
| Zdroj: | McMullin, C, Rajabi, N, Anker, M & Coles, M 2020, ' New Carbon-Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand ', Angewandte Chemie-International Edition . https://doi.org/10.1002/anie.202005301 |
| ISSN: | 1521-3773 1433-7851 |
| DOI: | 10.1002/anie.202005301 |
| Popis: | [K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [ 3 ] 2 . The dimeric alumoxane [K{Al(NON Dipp )(O)}] 2 reacts with carbon monoxide to afford the oxygen analogue of 3 , [K{Al(NON Dipp )(O 2 C)}] 2 [ 4 ] 2 containing the hitherto unknown ethenetetraolate ligand, [C 2 O 4 ] 4– . |
| Databáze: | OpenAIRE |
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