Wireless Electrochemiluminescence at Nafion–Carbon Microparticle Composite Films

Autor: Eoin Brennan, Emmanuel I. Iwuoha, Samantha F. Douman, Robert J. Forster
Rok vydání: 2017
Předmět:
Zdroj: Analytical Chemistry. 89:11614-11619
ISSN: 1520-6882
0003-2700
Popis: Thin films of a composite of nafion and carbon microparticles have been deposited on nonconducting substrates and their conductivity as well as their ability to generate electrochemiluminescence investigated. The films exhibit very low conductivity ( 65% (by volume) carbon particles using [Ru(bpy)3]2+ as the luminophore and tripropylamine as the coreactant, at an electric field of 14 V cm–1. Under these conditions, the complete film is sufficiently conducting to become polarized in the external electric field and the electrochemilu...
Databáze: OpenAIRE