In situ characterization of liquid network structures at high pressure and temperature using X-ray absorption spectroscopy coupled with the Paris-Edinburgh press
| Autor: | Angelika Dorothea Rosa, Max Wilke, J. Pohlenz, Yoshio Kono, C. de Grouchy, B. Cochain, Olivier Mathon, S. Pasternak, Tetsuo Irifune |
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| Přispěvatelé: | European Synchrotron Radiation Facility (ESRF), Institut des Sciences de la Terre de Paris (iSTeP), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
In situ
Phase transition Absorption spectroscopy Analytical chemistry 010502 geochemistry & geophysics 01 natural sciences X-ray absorption law.invention Viscosity law 0103 physical sciences 010306 general physics 0105 earth and related environmental sciences X-ray absorption spectroscopy Extended X-ray absorption fine structure Chemistry high pressure and temperature Condensed Matter Physics Paris-Edinburgh press Synchrotron Characterization (materials science) Condensed Matter::Soft Condensed Matter EXAFS Chemical physics [SDU]Sciences of the Universe [physics] Institut für Geowissenschaften liquid structure |
| Zdroj: | High Pressure Research High Pressure Research, 2016, 36, pp.332-347. ⟨10.1080/08957959.2016.1199693⟩ |
| DOI: | 10.1080/08957959.2016.1199693⟩ |
| Popis: | International audience; We review recent progress in studying structural properties of liquids using X-ray absorption spectroscopy coupled with the Paris-Edinburgh press at third-generation synchrotron facilities. This experimental method allows for detecting subtle changes in atomic arrangements of melts over a wide pressure-temperature range. It has been also employed to monitor variations of the local coordination environment of diluted species contained in glasses, liquids and crystalline phases as a function of the pressure and temperature. Such information is of great importance for gaining deeper insights into the physico-chemical properties of liquids at extreme condition, including the understanding of such phenomena as liquid-liquid phase transitions, viscosity drops and various transport properties of geological melts. Here, we describe the experimental approach and discuss its potential in structural characterization on selected scientific highlights. Finally, the current ongoing instrumental developments and future scientific opportunities are discussed. |
| Databáze: | OpenAIRE |
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