Contribution to the determination of tributyltin in water by stir bar sorptive extraction‒thermal desorption‒gas chromatography‒tandem mass spectrometry
| Autor: | Peter Tölgyessy, Slávka Nagyová |
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| Rok vydání: | 2022 |
| Předmět: |
History
Polymers and Plastics Organic Chemistry Reproducibility of Results Water General Medicine Biochemistry Gas Chromatography-Mass Spectrometry Industrial and Manufacturing Engineering Analytical Chemistry Tandem Mass Spectrometry Trialkyltin Compounds Business and International Management Water Pollutants Chemical |
| Zdroj: | Journal of Chromatography A. 1678:463358 |
| ISSN: | 0021-9673 |
| DOI: | 10.1016/j.chroma.2022.463358 |
| Popis: | An environmentally friendly method was developed to determine tributyltin (TBT) in water at the levels required by the European Union Water Framework Directive (EU WFD) using stir bar sorptive extraction (SBSE) in combination with thermal desorption‒gas chromatography‒triple quadrupole tandem mass spectrometry. The main focus of the method development was on addressing some aspects of reducing blank values (minimizing the use of chemicals, glassware cleaning, pretreatment of sorptive stir bars) and optimizing the SBSE procedure variables (sample volume, polarity of sample solution, extraction time). The performance of the method was studied in terms of linearity, matrix effect, method limits and accuracy (precision and trueness) using MilliQ, tap and surface water. TBT quantification limit for the studied matrices ranged from 0.049 to 0.055 ng L |
| Databáze: | OpenAIRE |
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