Crystal structure of (2Z, 5Z)-3-(4-methoxyphenyl)-2- (4-methoxyphenyl) imino -5- (E)-3-(2-nitrophenyl)allylidene - 1,3-thiazolidin-4-one
| Autor: | Rachida Rahmani, Ahmed Djafri, Jean-Claude Daran, Ayada Djafri, Abdelkader Chouaih, Fodil Hamzaoui |
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| Přispěvatelé: | Laboratory of Technology and Properties of Solids, Abdelhamid Ibn Badis University, University Abd elhamid Ibn Badis of Mostaganem, Laboratoire de chimie de coordination (LCC), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie de Toulouse (ICT-FR 2599), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Synthèse Organique Appliquée [Oran] (LSOA) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
crystal structure
Stereochemistry Stacking Crystal structure Dihedral angle 010402 general chemistry 010403 inorganic & nuclear chemistry Ring (chemistry) thiazolidinone 01 natural sciences Medicinal chemistry Research Communications lcsh:Chemistry Crystal chemistry.chemical_compound General Materials Science [CHIM.COOR]Chemical Sciences/Coordination chemistry Benzene Hydrogen bond General Chemistry Condensed Matter Physics hydrogen bonding thiazolidinone 0104 chemical sciences 3. Good health lcsh:QD1-999 chemistry Nitro π–π stacking |
| Zdroj: | Acta Crystallographica Section E Acta Crystallographica Section E, 2016, 72, pp.155-157. ⟨10.1107/s2056989016000207⟩ Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 2, Pp 155-157 (2016) |
| DOI: | 10.1107/s2056989016000207⟩ |
| Popis: | The thiazole ring of the title compound is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the title compound, C26H21N3O5S, the thiazole ring is nearly planar with a maximum deviation of 0.017 (2) Å, and is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π interactions link the molecules into a three-dimensional supramolecular architecture. Aromatic π–π stacking is also observed between the parallel nitrobenzene rings of neighbouring molecules, the centroid-to-centroid distance being 3.5872 (15) Å. |
| Databáze: | OpenAIRE |
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