Cleavage of territrems by alkaline hydrogen peroxide: Isolation and characterization of the aromatic moiety of territrems

Autor:	Kuo Huang Ling, Shih Chong Tsai, Yun Wen Peng, Chung Kuang Yang, Fu-Chuo Peng, Bai Jiun Chen
Rok vydání:	1987
Předmět:	Chemical structure Toxicology Cleavage (embryo) Microbiology Chemical reaction chemistry.chemical_compound chemistry Territrem B Territrem A Organic chemistry Aromatic moiety Hydrogen peroxide Biotechnology Benzoic acid
Zdroj:	Mycotoxin research. 3(2)
ISSN:	0178-7888
Popis:	The chemical reaction of cleavaging territrem B to give 3,4,5-trimethoxy benzoic acid by alkaline hydrogen peroxide was investigated. The method was applied for confirmation of the chemical structure of the aromatic moiety of territrem A, A’, B, and B’. The physicochemical properties of the aromatic cleavage product of territrem Aindicated the structure as 3,4-methylendioxy, 5-methoxy benzoic acid (or 4-methoxy, 6-carboxy, 1, 3-benzodioxole). The experiment also gave the evidences that territrem A and A’, on the other hand territrem B and B’ have the identical aromatic moieties on their structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::88e431745c06d123d3fde5fdb6d0ac22 https://pubmed.ncbi.nlm.nih.gov/23604939 Zobrazit plný text záznamu Full text from SpringerLink