H2as a fuel for flavin- And H2O2-dependent biocatalytic reactions
| Autor: | Lars Lauterbach, Frank Hollmann, Ammar Al-Shameri, Sébastien J.-P. Willot, Caroline E. Paul |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Hydrogenase
biology Chemistry Metals and Alloys General Chemistry Flavin group Electron source biology.organism_classification Highly selective equipment and supplies Combinatorial chemistry Catalysis Cofactor Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ralstonia Materials Chemistry Ceramics and Composites biology.protein Eutropha |
| Zdroj: | Chemical Communications, 56(67) |
| ISSN: | 1359-7345 |
| Popis: | The soluble hydrogenase from Ralstonia eutropha provides an atom efficient regeneration system for reduced flavin cofactors using H2 as an electron source. We demonstrated this system for highly selective ene-reductase-catalyzed CC-double bond reductions and monooxygenase-catalyzed epoxidation. Reactions were expanded to aerobic conditions to supply H2O2 for peroxygenase-catalyzed hydroxylations. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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