Simple tertiary phosphines to hexaphosphane ligands: Syntheses, transition metal chemistry and their catalytic applications
| Autor: | Maravanji S. Balakrishna, Sowmya Rao, Bimba Choubey |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Denticity
Phosphines Transition Metal Complexes Bis(2-(Diphenylphosphino)Phenyl) Ether chemistry.chemical_element Bite Angle Context (language use) Homogeneous catalysis Hydrogenation Reactions Ring (chemistry) Catalysis Transition metal 4-Coordinate Gold(I) Complexes Organic chemistry Sulfur Donor Action Chemistry Ligand Phosphorus General Chemistry Molecular-Structures Combinatorial chemistry Cross-Coupling Reactions Coordination Chemistry Pd-Ii Carbon-Carbon Coupling Reactions Copper(I) Complexes Multidentate Ligands |
| Zdroj: | IndraStra Global. |
| ISSN: | 2381-3652 |
| DOI: | 10.1007/s12039-012-0312-7 |
| Popis: | Designing efficient phosphorus-based ligands to make catalysts for homogeneous catalysis has been a great challenge for chemists. Despite a plethora of phosphorus ligands ranging from simple tertiary phosphines to polyphosphines are known, the enthusiasm to generate new ones is mainly due to the demand from industry for economical and robust catalytic system operational under normal atmospheric conditions. In this context, we have developed new synthetic methodologies for making unusual inorganic ring systems containing trivalent phosphorus centres, novel phosphorus-based multidentate and hybrid ligands and explored their rich transition metal chemistry and catalytic applications. We have also fine tuned a few existing ligand systems with donor functionalities to employ them in homogeneous catalysis. The details are summarized in this account. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|