The first steps toward C70 cycloadducts with a sulfur–fullerene bond: a selective sonochemical synthesis of single C70–1,4-oxathiane
| Autor: | Zemfira S. Kinzyabaeva, Glyus L. Sharipov, Denis Sh. Sabirov |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Fullerene
Organic Chemistry chemistry.chemical_element 02 engineering and technology Fullerene C70 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Sulfur Atomic and Molecular Physics and Optics Cycloaddition 0104 chemical sciences chemistry General Materials Science Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Fullerenes, Nanotubes and Carbon Nanostructures. 29:137-143 |
| ISSN: | 1536-4046 1536-383X |
| DOI: | 10.1080/1536383x.2020.1816975 |
| Popis: | C70 cycloadducts with sulfur–fullerene bond were previously unknown. We discovered that the sonochemical reaction of C70 with 1,2-hydroxythiols selectively produces the single 5,6-isomer of C70–1,4-oxathiane. The C70•– radical anion was detected with EPR as a key intermediate of the reaction. |
| Databáze: | OpenAIRE |
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