Double Ion Implantation and Pulsed Laser Melting Processes for Third Generation Solar Cells

Autor: Álvaro del Prado, Javier Olea, E. García-Hemme, R. García-Hernansanz, Ignacio Mártil, David Pastor, Germán González-Díaz, K. Sanchez, Perla Wahnón, Pablo Palacios
Rok vydání: 2013
Předmět:
Zdroj: International Journal of Photoenergy, Vol 2013 (2013)
International Journal of Photoenergy, ISSN 1110-662X, 2013, Vol. 2013
Archivo Digital UPM
Universidad Politécnica de Madrid
E-Prints Complutense: Archivo Institucional de la UCM
Universidad Complutense de Madrid
E-Prints Complutense. Archivo Institucional de la UCM
instname
ISSN: 1687-529X
1110-662X
DOI: 10.1155/2013/473196
Popis: In the framework of the third generation of photovoltaic devices, the intermediate band solar cell is one of the possible candidates to reach higher efficiencies with a lower processing cost. In this work, we introduce a novel processing method based on a double ion implantation and, subsequently, a pulsed laser melting (PLM) process to obtain thicker layers of Ti supersaturated Si. We perform ab initio theoretical calculations of Si impurified with Ti showing that Ti in Si is a good candidate to theoretically form an intermediate band material in the Ti supersaturated Si. From time-of-flight secondary ion mass spectroscopy measurements, we confirm that we have obtained a Ti implanted and PLM thicker layer of 135 nm. Transmission electron microscopy reveals a single crystalline structure whilst the electrical characterization confirms the transport properties of an intermediate band material/Si substrate junction. High subbandgap absorption has been measured, obtaining an approximate value of 104 cm−1in the photons energy range from 1.1 to 0.6 eV.
Databáze: OpenAIRE