Synthesis of azo chromophores containing a perfluorocyclo-alkenyl moiety and their second-order optical nonlinearity
| Autor: | Misa Kim, Masaki Matsui, Kazuo Tai, Hiroshige Muramatsu, Katsuyoshi Shibata, Kazuo Hirota, Kazumi Nakatsu, Kazumasa Funabiki, Michinori Tsuge, Hisayoshi Shiozaki, Masahiro Hosoda |
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| Rok vydání: | 1999 |
| Předmět: |
Chemistry
Stereochemistry Organic Chemistry Chromophore Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Intramolecular force visual_art Nitro visual_art.visual_art_medium Environmental Chemistry Order (group theory) Molecule Moiety Physical and Theoretical Chemistry Polycarbonate Methyl methacrylate |
| Zdroj: | ResearcherID |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/s0022-1139(99)00050-0 |
| Popis: | 1,2-Bis[4-[4-[ N -ethyl- N -(2-hydroxyethyl)amino]phenylazo]phenylthio]perfluorocyclopentene, having two independent intramolecular push-pull chromophores in a molecule, showed the highest second-order nonlinear coefficient ( d 33 ) among the cyclobutenyl, -pentenyl, -hexenyl, and cyclopentenyl nitro derivatives in both doped poly(methyl methacrylate) (PMMA) and polycarbonate (PC). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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