New avenues for mechanochemistry in zeolite science
| Autor: | Russell E. Morris, Daniel N. Rainer |
|---|---|
| Přispěvatelé: | European Research Council, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM |
| Rok vydání: | 2021 |
| Předmět: |
Scale (chemistry)
T-NDAS Nanotechnology 02 engineering and technology Microporous material Raw material QD Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry Chemistry Mechanochemistry Atom economy QD Gas separation 0210 nano-technology Zeolite |
| Zdroj: | Dalton Transactions (Cambridge, England : 2003) Dalton Transactions |
| ISSN: | 1477-9234 1477-9226 |
| Popis: | Zeolites are a class of microporous materials with tremendous value for large scale industrial applications such as catalysis, ion exchange, or gas separation. In addition to naturally ocurring variants, zeolites are made synthetically using hydrothermal synthesis, requiring temperatures beyond 100 °C and long reaction times up to weeks. Furthermore, specific applications may require more sophisticated synthesis conditions, expensive reagents, or post-synthetic modifications. Some of these issues can be tackled by using the reemerged technique of mechanochemistry. In 2014, Majano et al. reviewed the space and outlined several possibilities for the usage of mechanical forces in zeolite chemistry. Since then the field has seen many more publications employing mechanochemical methodology to further and improve the synthesis and properties of zeolite materials. The usage ranges from the activation of raw materials, rendering the synthesis of the widely used catalysts much more economical in terms of duration, atom efficiency, and production of waste, to post-synthetic modification of the materials leading to improved properties for target aplications. We present a short review of the advances that have been reported recently, highlight promising work and important studies, and give a perspective of potential future endeavours. Recent advances of mechanochemical methods in the field of zeolite science are reviewed and their future potential highlighted. |
| Databáze: | OpenAIRE |
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