Fourier transform infrared and Raman spectra of N-di-isopropylphosphorylguanidine (DPG)
| Autor: | Andréa de Moraes Silva, Judith Felcman, Claudio A. Téllez |
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| Rok vydání: | 2000 |
| Předmět: |
Aqueous solution
Molecular Structure Infrared Chemistry Analytical chemistry Spectrum Analysis Raman Tautomer Guanidines Atomic and Molecular Physics and Optics Spectral line Analytical Chemistry symbols.namesake Fourier transform Normal mode Spectroscopy Fourier Transform Infrared symbols Molecule Raman spectroscopy Instrumentation Spectroscopy |
| Zdroj: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. (8) |
| ISSN: | 1386-1425 |
| Popis: | The Fourier transform infrared and the Fourier transform Raman spectra of N-di-isopropylphosphorylguanidine (DPG) in the solid state and in aqueous solution were recorded and analyzed. Assuming Cs symmetry for different structural fragment of the molecule, the experimental and calculated band assignments of the ν(NH), δ(HNH), δ(CNH), ν(C N),ν(PN),ν(CN), ν(PO) and ν(OC) normal modes suggested that the DPG exists as a tautomeric contribution of the phosphorylamine (I) and N-phosphorylimine (II) structural forms. Download : Download high-res image (33KB) Download : Download full-size image |
| Databáze: | OpenAIRE |
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