DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
| Autor: | Aboubacary Sene, Gorgui Awa Seck, Libasse Diop |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
monochelating oxoanions
Technology Materials science lcsh:T Infrared discrete structures hydrogen bonds ir technic lattice benzene molecules monochelating oxoanions octahedral environments supramolecular architectures IR technic Photochemistry Engineering (General). Civil engineering (General) lcsh:Technology octahedral environments lcsh:TA1-2040 hydrogen bonds discrete structures TA1-2040 lcsh:Engineering (General). Civil engineering (General) lattice benzene molecules |
| Zdroj: | Journal of Engineering Studies and Research, Vol 23, Iss 2 (2017) Journal of Engineering Studies and Research, Vol 23, Iss 2 (2018) |
| ISSN: | 2344-4932 2068-7559 |
| Popis: | Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave as monochelating ligands, the environments around the metallic centres being octahedral. In two of the compounds, the benzene molecules obtained in situ are lattice. In all these structures when considering the cation involved in extra hydrogen bonds, a supramolecular architecture may be obtained. |
| Databáze: | OpenAIRE |
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