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Developments in electric vehicles and mobile electronic devices are promoting the demand for lithium-ion batteries with higher capacity and longer lifetime. The performances of lithium-ion batteries are crucially affected by cathode materials, among which ternary cathode materials are the most competitive option with the advantages of high capacity, safety, and cost-effectiveness. However, although high-nickel ternary cathode materials can achieve relatively high specific capacity, they generally have unsatisfactory stability during long-term cycling. In this study, the microscopic mechanisms of the cathode failure and the principle of coating modification in lithium-ion batteries have been comprehensively examined. It has been revealed that the irreversible capacity fading is mainly attributed to the interface chemical reaction, which reduces the transition-metal valence states and generates undesired disordered rock-salt phases. This structural phase transformation at the interface induces the dissolution of transition metals and results in irreversible capacity loss of the cathode. To restrain the occurrence of this process, a LiNbO |
