Diastereocontrolled Synthesis of trans- and cis-meso-Cyclopentene Aziridines

Autor:	Clare M. Rosser, Peter O'Brien, Darren Caine
Rok vydání:	2002
Předmět:	chemistry.chemical_compound Stereochemistry Chemistry Organic Chemistry Cyclopentene Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic Letters. 4:1923-1926
ISSN:	1523-7052 1523-7060
Popis:	[reaction: see text] The synthesis of novel substituted meso-aziridines is described: aziridination of 4-tert-butyldiphenylsilyloxy-cyclopent-1-ene is trans selective using Cu(I)/PhI=NSO(2)Ar and cis selective using PhNMe(3)(+)Br(3)(-)/Chloramine-T.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::880642d578332595c76a55faf810ace2 https://doi.org/10.1021/ol0259387 Zobrazit plný text záznamu