Heteropoly-13-palladates(II) [Pd(II)(13)(As(V)Ph)(8)O(32)](6-) and [Pd(II)(13)Se(IV)(8)O(32)](6-)
Autor: | Rosa Ngo Biboum, Vasanth Ramachandran, Natalya V. Izarova, Michael H. Dickman, Ulrich Kortz, Louis Nadjo, Naresh S. Dalal, Bineta Keita |
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Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Inorganic chemistry. 48(16) |
ISSN: | 1520-510X |
Popis: | Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry. |
Databáze: | OpenAIRE |
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