R-Group stabilization in methylated formamides observed by resonant inelastic X-ray scattering

Autor:	Miguel Ochmann, Vinícius Vaz da Cruz, Sebastian Eckert, Nils Huse, Alexander Föhlisch
Rok vydání:	2022
Předmět:	AMIDE BOND HYPERCONJUGATION ACID DYNAMICS ORIGIN Formamides Nitrogen X-Rays Materials Chemistry Metals and Alloys Ceramics and Composites Scattering Radiation General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). 58(63)
ISSN:	1364-548X
Popis:	The inherent stability of methylated formamides is traced to a stabilization of the deep lying amp; 963; framework by resonant inelastic X ray scattering at the nitrogen K edge. Charge transfer from the amide nitrogen to the methyl groups underlie this stabilization mechanism that leaves the aldehyde group essentially unaltered and explains the stability of secondary and tertiary amides
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::87ccf123452c55d325a04f14e315aa5e https://pubmed.ncbi.nlm.nih.gov/35848855 Zobrazit plný text záznamu