3D-Printed Fe/γ-Al2O3 Monoliths from MOF-Based Boehmite Inks for the Catalytic Hydroxylation of Phenol
| Autor: | Alma D. Salazar-Aguilar, Asuncion Quintanilla, Pablo López, Carla Martínez, Sofía M. Vega-Díaz, José A. Casas, Pilar Miranzo, M. Isabel Osendi, Manuel Belmonte |
|---|---|
| Přispěvatelé: | Agencia Estatal de Investigación (España), Ministerio de Ciencia e Innovación (España), Comunidad de Madrid, Consejo Superior de Investigaciones Científicas (España) |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| ISSN: | 1944-8252 1944-8244 2018-0950 |
| Popis: | [EN] The synthesis of dihydroxybenzenes (DHBZ), essential chemical reagents in numerous industrial processes, with a high degree of selectivity and yield from the hydroxylation of phenol is progressively attracting great interest in the catalysis field. Furthermore, the additive manufacturing of catalysts to produce 3D printed monoliths would provide additional benefits to enhance the DHBZ synthesis performance. Herein, 3D cellular Fe/γ-Al2O3 monoliths with a total porosity of 88% and low density (0.43 g·cm-3) are printed by Robocasting from pseudoplastic Fe-metal-organic frameworks (Fe-MOF)-based aqueous boehmite inks to develop catalytic monoliths containing a Fe network of dispersed clusters (≤5 μm), nanoclusters ( This work was supported by the following agencies and grants: Spanish Government under the project RTI2018-095052-BI00 (MICINN/AEI/FEDER, UE), Community of Madrid under project S2018/EMT-4341, and CSIC project I–COOP+ 2019 (ref. COOPB20405). P.L. acknowledges the Community of Madrid and the European Social Fund for the financing received through the contract PEJ-2019-AI/IND-14385. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|