Ruthenium(II)-Catalyzed CH Activation/Alkyne Annulation by Weak Coordination with O2as the Sole Oxidant

Autor:	Ana Cajaraville, Svenja Warratz, Benedikt Niepötter, Christoph Kornhaaß, Dietmar Stalke, Lutz Ackermann
Rok vydání:	2015
Předmět:	inorganic chemicals Annulation chemistry.chemical_element Alkyne Oxidative phosphorylation Alkenes Ruthenium Catalysis otorhinolaryngologic diseases Organic chemistry chemistry.chemical_classification Molecular Structure Hydrogen Bonding Ambient oxygen General Chemistry Benzoic Acid Aerobiosis 3. Good health Oxygen Key factors Isocoumarins chemistry Alkynes Oxidation-Reduction
Zdroj:	Angewandte Chemie International Edition. 54:5513-5517
ISSN:	1433-7851
DOI:	10.1002/anie.201500600
Popis:	Aerobic oxidative CH functionalizations of weakly coordinating benzoic acids have been accomplished with versatile ruthenium(II) biscarboxylates under ambient oxygen or air. Mechanistic studies identified the key factors controlling the elementary step of the oxidation of the ruthenium(0) complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8783044bb3dc28b651659daf6b4d8a10 https://doi.org/10.1002/anie.201500600 Zobrazit plný text záznamu Plný text