On the Relation between Population Kinetics and State-to-State Rate Coefficients for Vibrational Energy Transfer

Autor:	Ilya Litvin, E. I. Dashevskaya, E. E. Nikitin
Rok vydání:	2015
Předmět:	Chemical kinetics Physics Reaction rate constant Vibrational energy Population kinetics Physical chemistry Thermodynamics State (functional analysis) Physical and Theoretical Chemistry
Zdroj:	Zeitschrift für Physikalische Chemie
ISSN:	2196-7156 0942-9352
DOI:	10.1515/zpch-2015-0597
Popis:	The relation between time-dependent population of vibrational state and collision-induced state-to-state rate coefficients is discussed within the Landau–Teller kinetic equations for the relaxation of harmonic oscillators in a heat bath. In particular, the increase of the populations in the first and the second vibrational state of an initially cold oscillator shows a considerable variety of its relation to a single Landau–Teller state-to-state rate coefficient. It is suggested that this variety should be kept in mind when experimental studies of the relaxation of specific level are analyzed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8781a999d3ef03b80b51e6dae1fe8dd5 https://doi.org/10.1515/zpch-2015-0597 Zobrazit plný text záznamu