Syntheses and Structures of Novel Heteroarene-Fused Coplanar π-Conjugated Chromophores
| Autor: | Akula Balaiah, Ying-Ying Chu, Yi-Hung Liu, Liang-Chen Chi, Teng-Chih Chao, Shih-Feng Chiu, Yu Wang, Ken-Tsung Wong |
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| Rok vydání: | 2006 |
| Předmět: |
Annulation
Carbazole Stereochemistry Organic Chemistry Benzothiophene General Medicine Chromophore Conjugated system Ring (chemistry) Combinatorial chemistry Biochemistry chemistry.chemical_compound Crystallography chemistry Phenylene Intramolecular force Thiophene Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters. 8:5033-5036 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/ol061791y |
| Popis: | We have synthesized a series of novel coplanar chromophores in which heteroarenes, namely, thiophene, benzothiophene, and carbazole, were fused to neighboring phenylene ring(s) through intramolecular annulation via sp(3)-hybridized carbon atoms bearing two p-tolyl groups as peripheral substituents. The molecular configurations of the pi-conjugated backbones were determined by X-ray crystallographic analysis; the heteroarene-fused molecular frameworks of these novel molecules exhibit nearly coplanar conformations. [structure: see text] |
| Databáze: | OpenAIRE |
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