Dissipative Dynamic Covalent Chemistry (DDCvC) Based on the Transimination Reaction

Autor: Daniele Del Giudice, Matteo Valentini, Gabriele Melchiorre, Emanuele Spatola, Stefano Di Stefano
Rok vydání: 2022
Předmět:
Zdroj: Chemistry – A European Journal. 28
ISSN: 1521-3765
0947-6539
DOI: 10.1002/chem.202200685
Popis: This work reports that the composition of a dynamic library (DL) of interconverting imines can be controlled over time in a dissipative fashion by the addition of an activated carboxylic acid used as a chemical fuel. When the fuel is added to the DL, which is initially under thermodynamic equilibrium, the composition of the mixture dramatically changes and a new, dissipative (out of equilibrium) state is reached that persists until fuel exhaustion. Thus, a transient dissipative dynamic library (DDL) is generated that, eventually, reverts back to the initial DL when the fuel is consumed, closing a DL→DDL→DL cycle. The larger the amount of added fuel, the longer the time spent by the system in the DDL state. The transimination reaction is shown to be an optimal candidate for the realization of a dissipative dynamic covalent chemistry (DDCvC).
Databáze: OpenAIRE
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