Rates and Yields of Unimolecular Reactions Producing Highly Oxidized Peroxy Radicals in the OH-Induced Autoxidation of α-Pinene, β-Pinene, and Limonene
| Autor: | Ivan R. Piletic, Tadeusz E. Kleindienst |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | J Phys Chem A |
| ISSN: | 1520-5215 1089-5639 |
| DOI: | 10.1021/acs.jpca.1c07961 |
| Popis: | Recent ambient atmospheric measurements have detected highly oxygenated organic molecules (HOMs) at many sites and are a consequence of autoxidation processes occurring at ambient temperatures. Monoterpenes in particular have a propensity to autoxidize although they exhibit a wide range of HOM yields which may be due to a variety of reasons including reactions with different oxidants like OH and O(3), differing hydrogen (H) atom transfer or peroxy radical cyclization rates, numbers of available reaction pathways and/or energy loss processes for activated HO-monoterpene or O(3)-monoterpene adducts. In this work, the autoxidation mechanisms of (+)-α-pinene, (+)-β-pinene and (+)-limonene following initial OH oxidation and three successive O(2) additions are examined using density functional theory (DFT) to understand what accounts for the disparity. Rates of different potential autoxidation pathways initiated by OH addition or abstraction reactions are quantified using transition state theory (TST) and master equation approaches using the lowest energy conformers. OH abstraction reactions do not appreciably influence HOM production in the pinenes and limit autoxidation for limonene because the subsequent autoxidation reactions are slow while OH addition reactions are found to be the main route to HOMs for all three monoterpenes. Generally, faster autoxidation rates are computed in later unimolecular reactions that produce RO(7) radicals after OH addition (~10 s(−1) or greater) than rates for RO(5) peroxy radical production (0.2-7 s(−1)). Mechanistic pathways that form RO(7) peroxy radicals are similar for all three monoterpenes with a particular bicyclo RO(7) radical involving a five membered peroxide ring being favored for all three monoterpenes. The molar yields of RO(7) radicals are 4.6% (+10.0/−2.4), 3.8% (+9.1/−2.6), and 7.6% (+13.1/−4.9) for α-pinene, β-pinene and limonene respectively at 298 K and 1 ppb of NO and only significantly decline at NO concentrations exceeding 10 ppb. The higher yield for limonene relative to the pinenes is predominantly a consequence of the initial oxidation step: OH adducts of the bicyclic pinenes have to use the excess energy after OH addition to break one of the rings and make the molecule more flexible for autoxidation although this process is inefficient while one of the prominent OH adducts for monocyclic limonene does not have to do this and may add O(2) immediately before autoxidizing further. These insights may be used to guide a better representation of these processes in atmospheric models because they affect particulate matter (PM), NO(x) and ozone concentrations via enhanced production of low volatility species, less early generation NO(x) cycling and altered organic nitrate production. |
| Databáze: | OpenAIRE |
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