Fabrication and Characterization of Hybrid organic-inorganic electron extraction layers for polymer solar cells towards improved processing robustness and air stability
| Autor: | Christine Videlot-Ackermann, Riva Alkarsifi, Sadok Ben Dkhil, Nassira Chniba Boudjada, Donia Fredj, Xianjie Liu, Florent Pourcin, Olivier Margeat, Mats Fahlman, Mohamed Boujelbene, J. Ackermann, Volkan Kilinc |
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| Přispěvatelé: | Centre Interdisciplinaire de Nanoscience de Marseille (CINaM), Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS), Matériaux, Rayonnements, Structure (MRS), Institut Néel (NEEL), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Linköping University (LIU), Matériaux, Rayonnements, Structure (NEEL - MRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Photocurrent
Materials science business.industry Band gap Energy conversion efficiency 02 engineering and technology [CHIM.MATE]Chemical Sciences/Material chemistry [CHIM.INOR]Chemical Sciences/Inorganic chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 7. Clean energy 01 natural sciences Cathode Polymer solar cell 0104 chemical sciences law.invention Photoactive layer law Solar cell Optoelectronics General Materials Science 0210 nano-technology business Hybrid material ComputingMilieux_MISCELLANEOUS |
| Zdroj: | ACS Applied Materials & Interfaces ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2018, 10 (20), pp.17309-17317. ⟨10.1021/acsami.7b16297⟩ ACS Applied Materials & Interfaces, 2018, 10 (20), pp.17309-17317. ⟨10.1021/acsami.7b16297⟩ |
| ISSN: | 1944-8244 1944-8252 |
| DOI: | 10.1021/acsami.7b16297⟩ |
| Popis: | Organic–inorganic hybrid materials composed of bismuth and diaminopyridine are studied as novel materials for electron extraction layers in polymer solar cells using regular device structures. The hybrid materials are solution processed on top of two different low band gap polymers (PTB7 or PTB7-Th) as donor materials mixed with fullerene PC70BM as the acceptor. The intercalation of the hybrid layer between the photoactive layer and the aluminum cathode leads to solar cells with a power conversion efficiency of 7.8% because of significant improvements in all photovoltaic parameters, that is, short-circuit current density, fill factor, and open-circuit voltage, similar to the reference devices using ZnO as the interfacial layer. However when using thick layers of such hybrid materials for electron extraction, only small losses in photocurrent density are observed in contrast to the reference material ZnO of pronounced losses because of optical spacer effects. Importantly, these hybrid electron extraction l... |
| Databáze: | OpenAIRE |
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