Dendritic Structures Based on Bis(hydroxymethyl)propionic Acid as Platforms for Surface Reactions
| Autor: | Eva Malmström, Michael Malkoch, Eva Blomberg, Emma Östmark, Lubica Macakova, Tommaso Auletta |
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| Rok vydání: | 2005 |
| Předmět: |
chemistry.chemical_classification
Carboxylic acid Surfaces and Interfaces Condensed Matter Physics Acetonide Combinatorial chemistry Hydrolysis chemistry.chemical_compound chemistry Transition metal Electrochemistry Organic chemistry General Materials Science Hydroxymethyl Self-assembly Protecting group Layer (electronics) Spectroscopy |
| Zdroj: | Langmuir. 21:4512-4519 |
| ISSN: | 1520-5827 0743-7463 |
| DOI: | 10.1021/la047077b |
| Popis: | In this paper we present results related to the self-assembly of different generations of disulfide-cored 2,2-bis(hydroxymethyl)propionic acid-based dendritic structures onto gold surfaces. These molecular architectures, ranging from generation 1 to generation 3, contain removable acetonide protecting groups at their periphery that are accessible for hydrolysis with subsequent formation of OH-terminated surface-attached dendrons. The deprotection has been investigated in detail as a versatile approach to accomplish reactive surface platforms. A special focus has been devoted to the comparison of the properties of the layers formed by hydrolysis of the acetonide moieties directly on the surface and in solution, prior to the layer formation. |
| Databáze: | OpenAIRE |
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