Chiral Phosphinooxazolines with a Pentamethylferrocene BackboneSynthesis and Use as Ligands in Asymmetric Catalysis

Autor:	Felix M. Geisler, Guenter Helmchen
Rok vydání:	2006
Předmět:	Allylic rearrangement Chemistry Ligand Stereochemistry organic chemicals Organic Chemistry technology industry and agriculture Enantioselective synthesis Planar chirality Chirality (chemistry) Chemical synthesis Phosphinooxazolines Catalysis
Zdroj:	The Journal of Organic Chemistry. 71:2486-2492
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo0526136
Popis:	Novel phosphinooxazolines, containing a unit of central and a unit of planar chirality in a matched case combination, have been successfully tested in the Pd-catalyzed asymmetric allylic substitution with cycloalkenyl acetates as substrates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8674406c73a8502c57c2a80ab0e72d72 https://doi.org/10.1021/jo0526136 Zobrazit plný text záznamu