Electrochemical Difunctionalization of Styrenes via Chemoselective Oxo-Azidation or Oxo-Hydroxyphthalimidation

Autor: Fengzhi Zhang, Haobin Jiang, Feng Wang, Rongjin Zhu, Zenghui Ye
Rok vydání: 2021
Předmět:
Zdroj: Organic letters. 23(21)
ISSN: 1523-7052
Popis: Atom- and step-economic oxo-azidation and oxo-hydroxyphthalimidation of styrenes have been developed under mild electrolytic conditions, respectively. Various valuable alpha-azido or hydroxyphthalimide aromatic ketones were synthesized efficiently from readily available styrenes, azides, and N-hydroxyphthalimides. Mechanism studies show that two different pathways involved in these two transformations.
Databáze: OpenAIRE