Stable Push–Pull Disilene: Substantial Donor–Acceptor Interactions through the Si═Si Double Bond
| Autor: | Tomoyuki Kosai, Takeaki Iwamoto |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Double bond 010405 organic chemistry General Chemistry 010402 general chemistry Cleavage (embryo) 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Crystallography chemistry.chemical_compound Colloid and Surface Chemistry chemistry Absorption band Molecule Donor acceptor Push pull Disilene |
| Zdroj: | Journal of the American Chemical Society. 139:18146-18149 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/jacs.7b09989 |
| Popis: | The push–pull effect has been widely used to effectively tune π-electron systems. Herein, we report the synthesis and properties of 1-amino-2-boryldisilene 1 as the first push–pull disilene. Its spectroscopic and structural features show substantial interactions between the Si═Si double bond and the amino and boryl substituents. The π → π* absorption band of 1 is remarkably red-shifted compared to that of the corresponding alkyl-substituted disilene 2. Treatment of 1 with H2 resulted in the cleavage of two molecules of H2 under concomitant formation of the corresponding trihydridodisilane and hydroborane. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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