Control of Polaronic Behavior and Carrier Lifetimes via Metal and Anion Alloying in Chalcogenide Perovskites

Autor: Qiao-qiao Li, Luo Yan, Weibin Chu, Junjie He, Huanbo Luo, Thomas Frauenheim, Sergei Tretiak, Liujiang Zhou
Rok vydání: 2022
Předmět:
Zdroj: The Journal of Physical Chemistry Letters. 13:4955-4962
ISSN: 1948-7185
DOI: 10.1021/acs.jpclett.2c00880
Popis: Transition-metal perovskite chalcogenides (TMPCs) have emerged as lead-free alternatives to lead-halide perovskites and have been currently of increasing interest for optoelectronic applications because of their suitable band gaps, high carrier mobility, strong light absorption, and high stability. Here, we systematically report a study on the effects of Ti- and Se-alloying strategies on polaron behavior and carrier lifetimes in nonradiative recombination. Although such alloying can effectively tune the band gap of BaZrS
Databáze: OpenAIRE