Characterization of the diamond wire sawing process for monocrystalline silicon by raman spectroscopy and SIREX polarimetry

Autor: T. Kaden, Hans Joachim Möller, Sindy Würzner, Matthias Wagner, Martin Herms
Přispěvatelé: Publica
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Amorphous silicon
velocity
Control and Optimization
Materials science
diamond wire
silicon
wire velocity
wire cutting ability
stress imaging
stress-induced birefringence
amorphous phase
microcrack depth
Raman
SIREX
wire
Energy Engineering and Power Technology
02 engineering and technology
engineering.material
01 natural sciences
Monocrystalline silicon
Stress (mechanics)
cutting ability
symbols.namesake
chemistry.chemical_compound
Optics
Residual stress
Etching (microfabrication)
0103 physical sciences
Wafer
Electrical and Electronic Engineering
feedstock
Engineering (miscellaneous)
010302 applied physics
Renewable Energy
Sustainability and the Environment

business.industry
Diamond
imaging
021001 nanoscience & nanotechnology
Materialien - Solarzellen und Technologie
Kristallisation und Wafering
Silicium-Photovoltaik
chemistry
Photovoltaik
symbols
engineering
Optoelectronics
0210 nano-technology
Raman spectroscopy
business
Energy (miscellaneous)
Zdroj: Energies; Volume 10; Issue 4; Pages: 414
Popis: A detailed approach to evaluate the sub-surface damage of diamond wire-sawn monocrystalline silicon wafers relating to the sawing process is presented. Residual stresses, the presence of amorphous silicon and microcracks are considered and related to diamond wire velocity and cutting ability. In particular, the degree of amorphization of the wafer surface is analyzed, as it may affect the etching performance (texturing) during solar cell manufacture. Raman spectroscopy and Scanning Infrared Stress Explorer (SIREX) measurements are used independently as non-destructive, contactless optical characterization methods to provide stress imaging with high spatial resolution. Raman mappings show that amorphous silicon layers can occur inhomogeneously across the surface of diamond wire-sawn wafers. The Raman and SIREX results reveal a connection between a higher fraction of the amorphous phase, a more inhomogeneous stress distribution and a lower peak maximum of the stress difference on wafers, depending on both the wire wear and the wire velocity. SIREX line scans of the in-plane difference of the principal stress components ∆s taken across the sawing grooves show significant differences in magnitude and periodicity. Furthermore, the results are compared with the microcrack depth from the same investigation areas. The possibility to optimize the diamond wire sawing processes by analyzing the sub-surface stress of the wafers is offered by complementary use of both Raman and SIREX measurements.
Databáze: OpenAIRE