Metal Dilution Effects on the Reverse Spin Transition in Mixed Crystals of Type [Co(1-x)Zn(x)(C16-terpy)2](BF4)2 (x = 0.1-0.7)

Autor:	Ryo Ohtani, Saki Egawa, Masaaki Nakamura, Shinya Hayami, Hitomi Ohmagari, Leonard F. Lindoy, Manabu Nakaya
Rok vydání:	2016
Předmět:	010405 organic chemistry Chemistry Spin transition Analytical chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Dilution Inorganic Chemistry Metal Hysteresis visual_art visual_art.visual_art_medium Physical and Theoretical Chemistry
Zdroj:	Inorganic chemistry. 55(7)
ISSN:	1520-510X
Popis:	Metal dilution effects on reverse spin transition (rST) in mixed crystals of type [Co(1-x)Zn(x)(C16-terpy)2](BF4)2 (x = 0.1-0.7) were investigated by comparison with behavior of [Co(1-x)Fe(x)(C16-terpy)2](BF4)2 (x = 0.1-0.4). In the mixed crystals, the Zn complexes increased rST temperatures linearly with increasing values of x, without changing the hysteresis width, while the Fe complexes decreased rST temperatures. Moreover, the strength of the metal dilution effects in the CoZn mixed crystals is weaker than what occurs in the CoFe mixed crystals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8620b076c99ea1ae2628b2625a74260f https://pubmed.ncbi.nlm.nih.gov/26974553 Zobrazit plný text záznamu