New Safety-Catch Photolabile Protecting Group

Autor:	Christian G. Bochet, Emmanuel Riguet
Rok vydání:	2007
Předmět:	Chemistry Organic Chemistry Organic chemistry Physical and Theoretical Chemistry Protecting group Biochemistry Combinatorial chemistry
Zdroj:	Organic Letters. 9:5453-5456
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol702327c
Popis:	Photolabile protecting groups have proven their usefulness on many occasions. Their versions as linkers are however less attractive, as robustness and real orthogonality become critical issues. Safety-catch systems, where a preliminary activation phase is necessary, circumvent the problem of premature cleavage. In this work, we introduce a new safety-catch photolabile protecting group, whose cleavage requires the simultaneous presence of light and a chemical promoter.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::85fda5a745cd941a236b672908302ce4 https://doi.org/10.1021/ol702327c Zobrazit plný text záznamu