Covalent Organic Frameworks for Efficient Energy Electrocatalysis: Rational Design and Progress
| Autor: | Minshen Zhu, Oliver G. Schmidt, Kai Zhang, Hua Zhang, Shuiliang Chen |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
333
7 Materials science Rational design clean and sustainable energy conversions TJ807-830 Nanotechnology catalytic kinetics 02 engineering and technology General Medicine 010402 general chemistry 021001 nanoscience & nanotechnology Electrocatalyst clean fuels 01 natural sciences electrocatalysts Environmental technology. Sanitary engineering Renewable energy sources 0104 chemical sciences Covalent bond air batteries 0210 nano-technology covalent organic frameworks TD1-1066 Efficient energy use |
| Zdroj: | Advanced Energy & Sustainability Research, Vol 2, Iss 4, Pp n/a-n/a (2021) |
| ISSN: | 2699-9412 |
| Popis: | An efficient catalyst with a precisely designed and predictable structure is highly desired to optimize its performance and understand the mechanism beyond the catalytic activity. Covalent organic frameworks (COFs), as an emerging class of framework materials linked by strong covalent bonds, simultaneously allow precise structure design with predictable synthesis and show advantages of large surface areas, tunable pore sizes, and unique molecular architectures. Although the research on COF���based electrocatalysts is at an early age, significant progress has been made. Herein, the recent significant progress in the design and synthesis of COFs as highly efficient electrocatalysts for the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) is summarized. Design principles for COFs as efficient electrocatalysts are discussed by considering essential factors for catalyzing the OER, ORR, and HER processes at the molecular level. Herein, a summary on the in���depth understanding of the catalytic mechanism and kinetics limitations of COFs provides a general instruction for further exploring their vast potential for designing highly efficient electrocatalysts. |
| Databáze: | OpenAIRE |
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