A new family of oxime-based hexanuclear manganese(III) single molecule magnets with high anisotropy energy barriers
| Autor: | Eduard Cremades, Anna Proust, Michel Verdaguer, Kamal Boubekeur, José Martínez-Lillo, Eliseo Ruiz, Pierre Gouzerh, Lise-Marie Chamoreau, Adrian-Raul Tomsa, Fernanda F. Farias, Yanling Li, Miguel A. Novak |
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| Přispěvatelé: | Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Instituto de Fisica, Universidade de Rio de Janeiro, Caixa Postal 68528, Rio de Janeiro, RJ 21941-972, Departament de Quimica Inorganica, Universitat de Barcelona (UB), Institut Universitaire de France (IUF), Ministère de l'Education nationale, de l’Enseignement supérieur et de la Recherche (M.E.N.E.S.R.), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_element
Manganese 010402 general chemistry 01 natural sciences Catalysis Metal chemistry.chemical_compound Materials Chemistry Molecule [CHIM]Chemical Sciences ComputingMilieux_MISCELLANEOUS Anisotropy energy 010405 organic chemistry Metals and Alloys Solvation General Chemistry Oxime 0104 chemical sciences 3. Good health Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography chemistry visual_art Magnet Ceramics and Composites visual_art.visual_art_medium |
| Zdroj: | Chemical Communications Chemical Communications, Royal Society of Chemistry, 2010, 46 (28), pp.5106. ⟨10.1039/c0cc00485e⟩ Chemical Communications, 2010, 46 (28), pp.5106. ⟨10.1039/c0cc00485e⟩ |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | A magneto-structural study of two salicylamidoxime-based {Mn(6)} single-molecule magnets revealed that their anisotropy energy barriers, which can reach the current record for d-transition metal complexes, are strongly dependent upon the precise arrangement of ligands and the solvation state. |
| Databáze: | OpenAIRE |
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