Advances in Iodine(III)-Mediated Halogenations: A Versatile Tool to Explore New Reactivities and Selectivities

Autor:	Andreas M. Arnold, Anna Ulmer, Tanja Gulder
Rok vydání:	2016
Předmět:	010405 organic chemistry Chemistry Organic Chemistry Halogenation Nanotechnology General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences
Zdroj:	Chemistry - A European Journal. 22:8728-8739
ISSN:	0947-6539
DOI:	10.1002/chem.201600449
Popis:	Within the repertoire of organic chemical transformations, the halogenation of substrates is among the most versatile, reliable, and broadly applicable reactions. Although a multitude of different methods are known today, there is still a huge demand for novel and, in particular, catalytic halogenation methods that exhibit new reactivities and selectivities. The class of hypervalent iodanes meets exactly these needs and thus offers a great opportunity to fuel this highly desirable direction within the field of halogenation chemistry. This Concept gives a short overview of recent examples focusing on selective and/or mechanistically unusual halogenations.
Databáze:	OpenAIRE
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