High-temperature oxidation of nickel-based alloys and estimation of the adhesion strength of resulting oxide layers

Autor: Djar Oquab, Elena Fedorova, S. A. Khudonogov, Daniel Monceau
Přispěvatelé: Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Siberian Federal University (RUSSIA)
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Protection of Metals and Physical Chemistry of Surfaces.
ISSN: 2070-2051
Popis: The kinetics of isothermal oxidation (1100°C) of commercial nickel-based alloys with different content of sulfur (0.22–3.2 wt ppm) is studied. The adhesion strength in a metal/oxide system is estimated as a function of sulfur content and duration of high-temperature exposure. The scratch-test technique is proposed to quantitatively estimate the work of adhesion of resulting oxide films. It is found that the film microstructure is composed of an inner α-Al2O3 layer and an outer NiAl2O4 spinel layer, which are separated by discrete inclusions of TiO2. Residual stresses in the oxide film are experimentally determined by X-ray diffraction. spinel layer, which are separated by discrete inclusions of TiO2. Residual stresses in the oxide film are experimentally determined by X-ray diffraction
Databáze: OpenAIRE