Iridium Complexes of the Doubly Cyclometalated NHC Ligand IMes′′

Autor:	Janeth Navarro, Olga Torres, Marta Martín, Eduardo Sola
Rok vydání:	2011
Předmět:	Coordination sphere Ligand chemistry.chemical_element General Chemistry Photochemistry Biochemistry Small molecule Medicinal chemistry Catalysis IMes chemistry.chemical_compound Colloid and Surface Chemistry chemistry Reactivity (chemistry) Iridium
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja204522e
Popis:	Two consecutive C–H bond activations at the coordination sphere of Ir transform the commonly employed NHC ligand IMes into the new κ3-C fac-coordinating ligand IMes′′. The preparation and structure of Ir(III) complexes featuring this ligand together with selected reactions toward small molecules that illustrate their reactivity keys are described. This research was supported by the Spanish MICINN (Grants CTQ2009-08023 and Consolider Ingenio 2010 INTECAT CSD2006-0003) and Gobierno de Aragón (Group E79 and Project PI007/09).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::854e430ea34dc752ee137a0932382f7e https://doi.org/10.1021/ja204522e Zobrazit plný text záznamu