Syntheses and Solid‐State Structures of Bis(dialkylstibanyl)sulfanes and ‐telluranes

Autor:	Christoph Wölper, Dieter Bläser, Stephan Schulz, Stefan Heimann
Rok vydání:	2013
Předmět:	In situ crystallization Chemistry Fakultät für Chemie » Anorganische Chemie Intermolecular force Chemie Solid-state chemistry.chemical_element Recrystallization (metallurgy) Inorganic Chemistry Crystallography Chalcogen Antimony Antimony -- Laser-Assisted Crystallization -- Intermolecular Interactions ddc:540 Crystallite Diffractometer
Zdroj:	European Journal of Inorganic Chemistry. 2013:4909-4915
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.201300767
Popis:	Distibines Sb2R4 (R = Me, Et) react with elemental chalcogens (E = S, Se, Te) with insertion into the Sb–Sb bond and formation of the corresponding bis(dialkylstibanyl)sulfanes, ‐selenanes, and ‐telluranes (R2Sb)2E. The structures of (Et2Sb)2S (1), (Et2Sb)2Te (3), and (Me2Sb)2Te (4) were determined by single‐crystal X‐ray diffraction. The complexes either adopt a syn–syn (1, 4) or syn–anti conformation (3) in the solid state. In addition, the compounds have different intermolecular interaction modes, which depend on the bridging chalcogen and the organic substituent bound to the Sb atoms. Dedicated to Prof. Werner Uhl on the occasion of his 60th birthday.
Databáze:	OpenAIRE
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