A Complete Separation of Hexane Isomers by a Functionalized Flexible Metal Organic Framework
| Autor: | Hervé Jobic, Jacques Ollivier, Sébastien Rives, Patricia Horcajada, Emmanuel Magnier, Patricia A. P. Mendes, José A.C. Silva, Thomas Devic, Philippe Trens, Alírio E. Rodrigues, Hong Ren, Guillaume Maurin, Christian Serre |
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| Přispěvatelé: | Faculdade de Engenharia, Laboratory of Separation and Reaction Engineering (LSRE), Universidade do Porto, Institut Lavoisier de Versailles (ILV), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), IRCELYON-Approches thermodynamiques, analytiques et réactionnelles intégrées (ATARI), Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut Laue-Langevin (ILL), ILL |
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: |
Materials science
Hexane isomers Microporous material Neutron scattering Condensed Matter Physics Molecular sieve Electronic Optical and Magnetic Materials Biomaterials Hexane Molecular dynamics chemistry.chemical_compound Adsorption chemistry Functionalised MOFs Electrochemistry Physical chemistry Organic chemistry Metal-organic framework [PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph] Ternary operation |
| Zdroj: | Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP Advanced Functional Materials Advanced Functional Materials, Wiley, 2014, xx (xx), ⟨10.1002/adfm.201401974⟩ |
| ISSN: | 1616-301X 1616-3028 |
| DOI: | 10.1002/adfm.201401974⟩ |
| Popis: | The separation ability of branched alkane isomers (nHEX, 3MP, 22DMB) of the flexible and functionalized microporous iron(III) dicarboxylate MIL-53(Fe)-(CF3)(2) solid is evaluated through a combination of breakthrough experiments (binary or ternary mixtures), adsorption isotherms, X-ray diffraction temperature analysis, quasi-elastic neutron scattering measurements and molecular dynamics simulations. A kinetically controlled molecular sieve separation between the di-branched isomer of hexane 22DMB from a mixture of paraffins is achieved. The reported total separation between mono-and di-branched alkanes which was neither predicted nor observed so far in any class of porous solids is spectacular and paves the way towards a potential unprecedented upgrading of the RON of gasoline. |
| Databáze: | OpenAIRE |
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