Hybrid sulfur cycle for H2 production: A sensitivity study of the electrolysis step in a filter-press cell
| Autor: | Patrick Rivalier, Eric Chainet, Jean-Pierre Caire, Josselin Janvier, Sophie Charton |
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| Přispěvatelé: | CEA (DSV-DBJC-SMMCB), Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces (LEPMI ), Institut de Chimie du CNRS (INC)-Institut National Polytechnique de Grenoble (INPG)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Université Joseph Fourier - Grenoble 1 (UJF)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut National Polytechnique de Grenoble (INPG)-Institut de Chimie du CNRS (INC)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: |
Bubble
Inorganic chemistry Energy Engineering and Power Technology Thermodynamics 02 engineering and technology Overpotential 010402 general chemistry 01 natural sciences law.invention law [CHIM.ANAL]Chemical Sciences/Analytical chemistry [CHIM]Chemical Sciences Sensitivity (control systems) SO2 crossover Physics::Atmospheric and Oceanic Physics Electrolysis Renewable Energy Sustainability and the Environment Chemistry Cell voltage minimization Hybrid sulfur cycle 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Forced convection Anode Fuel Technology Balance equation Biphasic flow Hybrid Sulfur (HyS) cycle 0210 nano-technology Anodic overpotential |
| Zdroj: | International Journal of Hydrogen Energy International Journal of Hydrogen Energy, Elsevier, 2010, 35 (4), pp.1537-1547. ⟨10.1016/j.ijhydene.2009.12.046⟩ International Journal of Hydrogen Energy, 2010, 35 (4), pp.1537-1547. ⟨10.1016/j.ijhydene.2009.12.046⟩ |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2009.12.046⟩ |
| Popis: | International audience; The sensitivity of a depolarized SO2 electrolyzer to various operating parameters has been investigated through numerical modeling. A simplified kinetic expression was first derived to relate the anodic overpotential to both temperature and sulfuric acid concentration. This model allows the cell voltage variation with these two parameters to be studied.The effect of the two-phase parameters associated with hydrogen bubble production was then investigated. Parameters such as electrolyzer orientation, forced convection flow and bubble size were considered.Finally, an overall SO2 balance equation was derived to estimate the sensitivity of SO2 crossover to the operating conditions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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