Sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes
| Autor: | Jun-Qi Zhang, Wen-Ting Wei, Meiling Zhu, Dong-Kai Wang, Shi-Ping Wu, Ting Li, Hongxing Zheng, Qing-Qing Kang, Guo-Ping Ge |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Sulfonyl
chemistry.chemical_classification Reaction conditions 010405 organic chemistry High selectivity Metals and Alloys Substrate (chemistry) General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Radical cyclization Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Functional group Materials Chemistry Ceramics and Composites |
| Zdroj: | Chemical Communications. 57:8288-8291 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d1cc03252f |
| Popis: | A novel sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes has been described for the first time. High selectivity and efficiency, mild reaction conditions, excellent functional group compatibility, and broad substrate scope are the attractive features of this synthetic protocol, which provides a unique platform for precise radical cyclization. |
| Databáze: | OpenAIRE |
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