Autor: |
Zongyu Wang, Laiying Jing, Xiang Zheng, Zhengguan Xu, Yapeng Yuan, Xuehua Liu, Aiping Fu, Yu-Guo Guo, Hongliang Li |
Rok vydání: |
2023 |
Předmět: |
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Zdroj: |
Journal of Colloid and Interface Science. 629:511-521 |
ISSN: |
0021-9797 |
DOI: |
10.1016/j.jcis.2022.09.087 |
Popis: |
The huge volumetric expansion (300 %) of Si that occurs during the charge-discharge process makes it to have poor cycling ability and weak stable structure. These factors are considered as critical obstacles to the further development of Si as anode for lithium-ion batteries (LIBs). Herein, novel 3D interpenetrating microspheres, i.e., Si@C-CNTs, which consist of silicon nanoparticles interpenetrated with carbon nanotubes (CNTs) and stuck with amorphous carbon (C) have been designed and prepared via a spray-drying assisted approach. As anode of LIBs, Si@C-CNTs microspheres can achieve high silicon loadings of around 86 % and a high initial coulomb efficiency of 80.8 %. The electrodes maintain a reversible specific capacity of 1585.9mAh/g at 500 mA g |
Databáze: |
OpenAIRE |
Externí odkaz: |
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