Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis
| Autor: | Rafał Gawin, Paweł Dąbrowski, Krzysztof Skowerski, Anna Kozakiewicz, Piotr A. Guńka |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Olefin metathesis 010405 organic chemistry Communication ethenolysis chemistry.chemical_element General Chemistry General Medicine 010402 general chemistry 01 natural sciences Communications Catalysis Ruthenium 0104 chemical sciences carbenes indenylidenes chemistry.chemical_compound chemistry Olefin Metathesis Polymer chemistry Organic chemistry ruthenium Carbene Alkyl |
| Zdroj: | Angewandte Chemie International Edition Angewandte Chemie (International Ed. in English) |
| ISSN: | 0044-8249 |
| Popis: | Thestate-of-the-art in olefin metathesis is applicationof N-heterocycliccarbene (NHC)-containing ruthenium alkylidenes for the formationof internalC=C bonds and of cyclic alkyl amino carbene (CAAC)-containing rutheniumbenzylidenesin the production of terminalolefins. A straightforward synthesisof bis(CAAC)Ru indenylidenecomplexes,which are highlyeffectivein the formationof both terminal andinternalC=C bonds at loadings as lowas 1ppm,is now reported. |
| Databáze: | OpenAIRE |
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