Towards a Sustainable Synthesis of Oxymethylene Dimethyl Ether by Homogeneous Catalysis and Uptake of Molecular Formaldehyde

Autor:	Ingo Krossing, Harald Scherer, Ines Lindner, Robin J. White, Samuel M. Fehr, Eberhard Jacob, Valentin Dybbert, Achim Schaadt, M. Ouda, Daniel Himmel, Andreas Peter
Přispěvatelé:	Publica
Rok vydání:	2018
Předmět:	010405 organic chemistry Formaldehyde Homogeneous catalysis General Chemistry General Medicine 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Monomer chemistry Synthetic fuel Anhydrous Organic chemistry Dimethyl ether Dimethoxymethane
Zdroj:	Angewandte Chemie. 130:9605-9608
ISSN:	0044-8249
DOI:	10.1002/ange.201802247
Popis:	Oxymethylene dimethyl ethers (OMEn; CH3(‐OCH2‐)nO‐CH3, n=3-5) are a novel class of sustainable synthetic fuels, which are of increasing interest due to their soot‐free combustion. Herein a novel anhydrous OMEn synthesis route is presented. Catalyzed by trimethyloxonium salts, dimethoxymethane takes up monomeric gaseous formaldehyde instantaneously and forms high purity OMEn at temperatures of 25-30 °C. This new anhydrous approach using molecular formaldehyde and catalytic amounts of highly active trimethyloxonium salts represents a promising new step towards a sustainable formation of OMEn emanating from CO2 and H2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8375ca067909a44b68155729f626ed18 https://doi.org/10.1002/ange.201802247 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.