Regioselective Reductive Opening of Benzylidene Acetals with Dichlorophenylborane/Triethylsilane: Previously Unreported Side Reactions and How to Prevent Them

Autor:	Jérôme Hénault, Pauline Quellier, Maxime Mock-Joubert, Christine Le Narvor, Aurélien Alix, David Bonnaffé
Rok vydání:	2022
Předmět:	Acetals Organic Chemistry Silanes Benzylidene Compounds Oxidation-Reduction
Zdroj:	The Journal of organic chemistry. 87(2)
ISSN:	1520-6904
Popis:	Arylidene acetals are widely used protecting groups, because of not only the high regioselectivity of their introduction but also the possibility of performing further regioselective reductive opening in the presence of a hydride donor and an acid catalyst. In this context, the Et
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::833e61e95ef3be46f00f77ea9958fd2b https://pubmed.ncbi.nlm.nih.gov/35015527 Zobrazit plný text záznamu